Personally I would take the lead off of the starting battery and run it to the other trolling battery. At least, that's what I do. Your outboard should charge the starting battery. I have never had to charge my starting battery on any boats that I have owned.
As far as your question---I am sure you can do it, but you will be splitting the amount of amps between batteries and it can take twice as long to charge them up. Can't remember off hand if you want to do that in series or in paralell???



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